The German wrestlers are still waiting for their second medal at the World Championships in Serbia.
Christopher Kramer (up to 60 kg) and Michael Widmayer (72 kg) each failed in the quarter-finals in Belgrade on the seventh day of the competition.
Light heavyweight Peter Öhler (up to 97 kg), however, still has a chance in the repechage round on Saturday because his opponent made it to the final.
Anastasia Blayvas (up to 55 kg) won bronze for the German team on Tuesday.